Flux-assisted polytypism in the [Na<sub>2</sub>Cl]GaQ<sub>2</sub> heterolayered salt-inclusion chalcogenide family-Reference-Cited by-同舟云学术

Flux-assisted polytypism in the [Na₂Cl]GaQ₂ heterolayered salt-inclusion chalcogenide family

Published:2023 Issue:15 Volume:25 Page:2307-2312
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Berseneva Anna A.¹^ORCID,Klepov Vladislav V.¹²,Tisdale Hunter B.¹^ORCID,zur Loye Hans-Conrad¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, 29208, USA

2. Department of Chemistry, University of Georgia, Athens, Georgia, 30602, USA

Abstract

Via flux-assisted synthesis, we discovered three novel salt-inclusion materials, t-[Na2Cl]GaS2, o-[Na2Cl0.9I0.1]GaSe2, and t-[Na2Cl0.9I0.1]GaSe2, and two new selenides, Na2GaSe3 and Na4Ga2Se5, by changing the flux from NaCl/NaI to NaBr/NaI, respectively.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D3CE00074E

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