Photochemical pump and NMR probe to monitor the formation and kinetics of hyperpolarized metal dihydrides
Author:
Affiliation:
1. Centre for Hyperpolarisation in Magnetic Resonance
2. Department of Chemistry
3. York Science Park
4. University of York
5. York
6. York YO10 5DD
7. UK
Abstract
Pulsed-laser experiments validate photochemical pump-NMR probe spectroscopy for monitoring the rate of rapid H2 oxidative addition to a metal centre.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC01956K
Reference36 articles.
1. Laser Flash Photolysis Generation of High-Valent Transition Metal−Oxo Species: Insights from Kinetic Studies in Real Time
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5. The theory and practice of hyperpolarization in magnetic resonance using parahydrogen
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