Centred nine-metal rings of lanthanides-Reference-Cited by-同舟云学术

Centred nine-metal rings of lanthanides

Published:2014 Issue:12 Volume:50 Page:1438-1440
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Zangana Karzan H.¹²³,Pineda Eufemio Moreno¹²³,McInnes Eric J. L.¹²³,Schnack Jürgen⁴⁵⁶,Winpenny Richard E. P.¹²³

Affiliation:

1. School of Chemistry and Photon Science Institute

2. The University of Manchester

3. Manchester M13 9PL, UK

4. Department of Physics

5. The University of Bielefeld

6. Bielefeld, Germany

Abstract

Two new decametallic lanthanide complexes are reported, that are large odd-numbered rings with a further central metal site. This type of structure appears to be unprecedented. Magnetic studies show weak exchange interactions between the spin sites for the {Gd₁₀} disc.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC48708C

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