Facile synthesis of anhydrous alkaline earth metal dodecaborates MB12H12 (M = Mg, Ca) from M(BH4)2-Reference-Cited by-同舟云学术

Facile synthesis of anhydrous alkaline earth metal dodecaborates MB12H12 (M = Mg, Ca) from M(BH4)2

Published:2015 Issue:36 Volume:44 Page:15882-15887
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

He Liqing¹²³⁴⁵,Li Hai-Wen⁶³⁴⁵⁷,Tumanov Nikolay⁸⁹¹⁰¹¹,Filinchuk Yaroslav⁸⁹¹⁰¹¹,Akiba Etsuo¹²³⁴⁵

Affiliation:

1. Department of Mechanical Engineering

2. Faculty of Engineering

3. Kyushu University

4. Fukuoka 819-0395

5. Japan

6. International Research Center for Hydrogen Energy

7. WPI International Institute for Carbon-Neutral Energy Research (WPI-I2CNER)

8. Institute of Condensed Matter and Nanosciences

9. Université catholique de Louvain

10. Louvain-la-Neuve 1348

11. Belgium

Abstract

Thermal decomposition of MB₁₂H₁₂ (M = Mg, Ca) forms H-deficient monomers MB₁₂H_12−x containing icosahedral B₁₂ skeletons and is followed by the formation of (MB_yH_z)_n polymers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02343B

Reference36 articles.

1. Complex Hydrides for Hydrogen Storage

2. Recent Progress in Metal Borohydrides for Hydrogen Storage

3. Tailoring properties of borohydrides for hydrogen storage: A review

4. Toward high-mobility organic field-effect transistors: Control of molecular packing and large-area fabrication of single-crystal-based devices

5. Experimental studies on intermediate compound of LiBH4

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