DFT insights into the Ni-catalyzed regioselective hydrocarboxylation of unsaturated alkenes with CO2-Reference-Cited by-同舟云学术

DFT insights into the Ni-catalyzed regioselective hydrocarboxylation of unsaturated alkenes with CO2

Published:2021 Issue:42 Volume:50 Page:15084-15093
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shao Yifan¹,Nie Wan²,Yao Chengyu¹,Ye Lina¹,Yu Haizhu¹³^ORCID

Affiliation:

1. Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei 230601, P. R. China

2. Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

3. Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, P. R. China

Abstract

The substituted benzylic group promotes the β-H transfer and subsequent α-carboxylation for aromatic olefins, while β-carboxylation is predominant for aliphatic alkenes due to the disfavored H-transfer (lower proton affinity of aliphatic alkenes).

Funder

Institute of Physical Science and Information Technology, Anhui University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02486H

Reference104 articles.

1. Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexes

2. Transformation of Carbon Dioxide