Time-evolved, far-red, circularly polarised luminescent polymer aggregates endowed with sacrificial helical Si–Si bond polymers
Author:
Affiliation:
1. Graduate School of Materials Science
2. Nara Institute of Science and Technology
3. Ikoma
4. Japan
Abstract
Non-charged helical polysilanes (PSi) were spontaneously endowed with CPL on the order of gem = ±0.02 at 700 nm when non-helical red- and far-red π-conjugated polymeric (PF8DBT) aggregates were employed after ageing at 20–25 °C for 24 h, followed by PSi-selective photoscissoring at 313 nm for 60 s.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QM/C7QM00096K
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