Synthesis and structures of the heavier alkali metal alkyls; the X-ray structures of [Na(µ-R)]∞and [Rb(µ-R)(pmdeta)]2[R = CH(SiMe3)2, pmdeta =(Me2NCH2CH2)2NMe]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1993/C3/C39930001386
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1. Sodium, Potassium, Rubidium, and Cesium: X-Ray Structurai Analysis of Their Organic Compounds
2. Bivalent germanium, tin, and lead 2,6-di-tert-butylphenoxides and the crystal and molecular structures of M(OC6H2Me-4-But2-2,6)2 (M = Ge or Sn)
3. Molecular structures of bis(trimethylsilyl)methyl-lithium [(LiR)n, R = CH(SiMe3)2] in the vapour (gas-phase electron diffraction: a monomer, n= 1) and the crystal (X-ray: a polymer, n=∞)
4. Subvalent Group 4B metal alkyls and amides. Part 8. Germanium and tin carbene analogues MR2[M = Ge or Sn, R = CH(SiMe3)2]: syntheses and structures in the gas phase (electron diffraction); molecular-orbital calculations for MH2 and GeMe2
5. Synthesis and structural characterisation of the first neutral homoleptic lanthanide metal(III) alkyls: [LnR3][Ln = La or Sm, R = CH(SiMe3)2]
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