Synthesis and structural-bonding analysis of the [Ni8(PCMe3∥2(PMe)2(CO)12]nseries (n= 0,2–): polyhedral rearrangement of the electron-precise (µ5-Ni)2(µ4-P)2-tetracapped Ni6P2cuneane framework in the neutral parent into an electron-delocalized noncentred Ni8P4icosahedral cage in the dianion by a two-electron chemical reduction
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1993/C3/C39930000585
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1. An octanuclear coordination cage with a ‘cuneane’ core—a topological isomer of a cubic cage;Dalton Transactions;2011
2. The possible role of metal carbonyl clusters in nanoscience and nanotechnologies;Coordination Chemistry Reviews;2006-06
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4. Bonding Analysis in Inorganic Transition-Metal Cubic Clusters. 3. Metal-Centered Tetracapped M9(μ5-E)4Ln Species with a Tetragonal Distortion;Inorganic Chemistry;1998-02-12
5. Main Group–Transition Metal Cluster Compounds of the Group 15 Elements;Advances in Organometallic Chemistry;1998
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