Catalytic ammonia synthesis on HY-zeolite-supported angstrom-size molybdenum cluster-Reference-Cited by-同舟云学术

Catalytic ammonia synthesis on HY-zeolite-supported angstrom-size molybdenum cluster

Published:2024 Issue:8 Volume:15 Page:2914-2922
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kamiguchi Satoshi¹²^ORCID,Asakura Kiyotaka³^ORCID,Shibayama Tamaki⁴^ORCID,Yokaichiya Tomoko⁵^ORCID,Ikeda Tatsushi⁵^ORCID,Nakayama Akira⁵^ORCID,Shimizu Ken-ichi³^ORCID,Hou Zhaomin¹²^ORCID

Affiliation:

1. Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan

2. Organometallic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan

3. Institute for Catalysis, Hokkaido University, Sapporo, 001-0021, Japan

4. Center for Advanced Research of Energy Conversion Materials, Hokkaido University, Sapporo, 060-8628, Japan

5. Department of Chemical System Engineering, Graduate School of Engineering, The University of Tokyo, Tokyo, 113-8656, Japan

Abstract

A molybdenum halide cluster complex is converted to an angstrom-size metal cluster on HY zeolite. The cluster efficiently catalyzes ammonia synthesis owing to high N2 activation ability brought by cooperation of the multiple molybdenum sites.

Funder

Hokkaido University

Tohoku University

Aichi Science and Technology Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05447K

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