Complex transition metal hydrides incorporating ionic hydrogen: thermal decomposition pathway of Na2Mg2FeH8 and Na2Mg2RuH8-Reference-Cited by-同舟云学术

Complex transition metal hydrides incorporating ionic hydrogen: thermal decomposition pathway of Na2Mg2FeH8 and Na2Mg2RuH8

Published:2015 Issue:12 Volume:17 Page:8276-8282
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Humphries Terry D.¹²³⁴,Matsuo Motoaki⁵²³⁴,Li Guanqiao¹²³⁴,Orimo Shin-ichi¹²³⁴⁵

Affiliation:

1. WPI-Advanced Institute for Materials Research

2. Tohoku University

3. Aoba-ku

4. Japan

5. Institute for Materials Research

Abstract

The optimised syntheses of Na₂Mg₂FeH₈ and Na₂Mg₂RuH₈ are reported and their thermal decomposition pathways established. The enthalpy and entropy of each decomposition step has been determined by PCI measurements.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP00258C

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