An environmentally friendly route for grafting of molybdenum carbonyl onto a diaminosilane-modified SBA-15 molecular sieve and its catalytic behaviour in olefin epoxidation

Author:

Baskaran Thangaraj12345,Kumaravel Raju12345,Christopher Jayaraj6785,Ajithkumar Thalasseril G.910115,Sakthivel Ayyamperumal12345

Affiliation:

1. Department of Chemistry

2. Inorganic Materials and Catalysis Laboratory

3. University of Delhi

4. New Delhi-110007

5. India

6. Indian Oil Corporation Ltd

7. R&D Centre

8. Faridabad-12100

9. Central NMR Facility

10. CSIR-National Chemical Laboratory

11. Pune-411008

Abstract

Molybdenum carbonyl (Mo(CO)6) grafted onto a diaminosiloxane functionalized SBA-15 surface and showed promising activity for epoxidation of olefins.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference51 articles.

1. R. A. Sheldon and J. K.Kochi, Metal-catalyzed oxidation of organic compounds, Academic Press, New York, 1981

2. C. L. Hill , in Advances in Oxygenated Processes, ed. A. L. Baumstark, JAI, London, 1988, vol. 1, p. 1

3. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates

4. Epoxidation of olefins with homogeneous catalysts – quo vadis?

5. A. Sakthivel and M.Sathiyendiran, in Molybdenum and its compounds, ed. V. S. Saji and S. I Lopatin, Nova Science Publishers, 2014, ISBN: 978-1-63321-210-7 at press and the reference therein

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