Phosphorescent Pt(ii) acetylacetonate complexes bearing 9-(pyrimidin-2-yl)-9H-carbazole ligand: syntheses, photophysical properties and OLED applications

Author:

Yao Haibo12,Yuan Lequn1,Pei Ling2,Shen Yunjun1ORCID,Zhang Yuzhen1ORCID,Zhou Liang3ORCID,Bian Hedong1ORCID

Affiliation:

1. Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products, School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, Guangxi, China

2. Engineering Research Center for Industrial Wastewater Treatment and Reuse of Shandong Province, School of Chemical Engineering and Safety, Binzhou University, Binzhou 256603, Shandong, China

3. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

Abstract

Complexes Pt(TBPCH)(dpmn) 2a and Pt(TBPCH)(dnmn) 4a were prepared for fabricating OLED devices. The devices using 2a emitted at 525 nm with an EQEmax of 4.0% at CIE coordinates of (0.34, 0.51), and the devices using 4a emitted at 585 nm with an EQEmax of 15.1% at CIE coordinates of (0.50, 0.48).

Funder

Natural Science Foundation of Guangxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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