DMSO-promoted direct δ-selective arylation of p-quinone methenylpiperidine bearinides to generate fuchsones under metal-free conditions by employing p-QMs themselves or substituted phenols as aryl sources

Author:

Wang Kunpeng1,Li Jingping1,Zhang Haoxiang1,Chen Yan1,Li Mengfan1,Xu Junju23,Liao Benren4,Yi Weiyin1ORCID

Affiliation:

1. School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, P. R. China

2. College of Tabacco Science, Yunnan Agricultural University, Kunming 650201, P. R. China

3. Key Laboratory of Sustainable Utilization of Plateau characteristic spice plant resources, Education Department of Yunnan Province 650201, P. R. China

4. Shanghai No. 4 Reagent Chemical Co., Ltd, Shanghai 201512, P. R. China

Abstract

Two DMSO-promoted protocols for direct δ-selective arylation synthesis of symmetrical and unsymmetrical fuchsones from p-QMs under metal-free conditions were described.

Funder

Shanghai Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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