Oxalamide-based bisdiamidophosphites: synthesis, coordination, and application in asymmetric metallocatalysis

Author:

Gavrilov Konstantin N.1234ORCID,Mikhel Igor S.5674ORCID,Zheglov Sergey V.1234ORCID,Gavrilov Vladislav K.1234ORCID,Chuchelkin Ilya V.1234ORCID,Firsin Ilya D.1234ORCID,Birin Kirill P.5674ORCID,Pytskii Ivan S.5674ORCID,Paseshnichenko Ksenia A.1894ORCID,Tafeenko Victor A.1894ORCID,Chernyshev Vladimir V.56741ORCID,Shiryaev Alexei A.1011124ORCID

Affiliation:

1. Department of Chemistry

2. Ryazan State University named for S. Yesenin

3. 390000 Ryazan

4. Russian Federation

5. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry

6. Russian Academy of Sciences

7. Moscow

8. M. V. Lomonosov Moscow State University

9. 119991 Moscow

10. Department of Organic and Ecological Chemistry

11. University of Tyumen

12. 625003 Tyumen

Abstract

A new group of P*-chiral bisdiamidophosphites has been developed for Pd- and Rh-catalyzed asymmetric reactions with good to excellent enantioselectivities.

Funder

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference130 articles.

1. J. M. Brown , in Comprehensive Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and Y. Yamamoto , Springer , Berlin , 1999 , vol. 1 , pp. 121–182

2. T. Ohkuma , M.Kitamura and R.Noyori , in Catalytic Asymmetric Synthesis , ed. I. Ojima , Wiley-VCH , New York , 2000 , pp. 1–110

3. Modular Phospholane Ligands in Asymmetric Catalysis

4. Phosphorus Ligands in Asymmetric Catalysis , ed. A. Börner , Wiley-VCH , Weinheim , 2008

5. Copper‐Catalyzed Asymmetric Allylic Alkylation

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