Reversing the relative 3MLCT–3MC order in Fe(ii) complexes using cyclometallating ligands: a computational study aiming at luminescent Fe(ii) complexes-Reference-Cited by-同舟云学术

Reversing the relative 3MLCT–3MC order in Fe(ii) complexes using cyclometallating ligands: a computational study aiming at luminescent Fe(ii) complexes

Published:2015 Issue:30 Volume:44 Page:13498-13503
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dixon Isabelle M.¹²³⁴,Alary Fabienne¹²³⁴,Boggio-Pasqua Martial¹²³⁴,Heully Jean-Louis¹²³⁴

Affiliation:

1. Laboratoire de Chimie et Physique Quantiques

2. UMR 5626 CNRS/Université Paul Sabatier-Toulouse III

3. Toulouse

4. France

Abstract

Positioning two cyclometallating rings on the periphery of tridentate ligands has allowed us to design for the first time an iron(ii) complex bearing the lowest triplet state of MLCT nature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01214G

Reference26 articles.

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4. Solvent tuning of the excited-state properties of (2,2'-bipyridine)tetracyanoferrate(II): direct observation of a metal-to-ligand charge-transfer excited state of iron(II)

5. Towards longer-lived metal-to-ligand charge transfer states of iron(ii) complexes: an N-heterocyclic carbene approach

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