A mononuclear Ni(ii) complex: a field induced single-molecule magnet showing two slow relaxation processes-Reference-Cited by-同舟云学术

A mononuclear Ni(ii) complex: a field induced single-molecule magnet showing two slow relaxation processes

Published:2015 Issue:28 Volume:44 Page:12484-12487
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Miklovič Jozef¹²³⁴⁵,Valigura Dušan¹²³⁴⁵,Boča Roman¹²³⁴⁵,Titiš Ján¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. FPV

3. University of SS Cyril and Methodius

4. 917 01 Trnava

5. Slovakia

Abstract

The complex [Ni(pydc)(pydm)]·H₂O, pyridine-2,6-dicarboxylato-2,6-bis(hydroxymethyl)pyridine-nickel(ii) monohydrate, possesses a sizable magnetic anisotropy, D/hc = −14 cm⁻¹. It displays superparamagnetic behavior in an applied external field that culminates at B_DC = 0.2 T.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01213A

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