Dielectric response of light, heavy and heavy-oxygen water: isotope effects on the hydrogen-bonding network's collective relaxation dynamics
Author:
Affiliation:
1. Department of Molecular Spectroscopy
2. Max Planck Institute for Polymer Research
3. Ackermannweg 10
4. 55128 Mainz
5. Germany
6. Department of Chemistry
7. University of Zurich
8. 8057 Zurich
9. Switzerland
Abstract
Dielectric relaxation experiments on light, heavy-, and heavy-oxygen water reveal that classical mass effects on the reorientational relaxation of water can be accounted for by a translational mass factor.
Funder
Alexander von Humboldt-Stiftung
Deutsche Forschungsgemeinschaft
H2020 European Research Council
Max-Planck-Gesellschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06460B
Reference57 articles.
1. Physical properties of heavy-oxygen water. Absolute viscosity of H218O between 15 and 35°C
2. Thermal Offset Viscosities of Liquid H2O, D2O, and T2O
3. Isotope effects and the thermal offset effect for diffusion and viscosity coefficients of liquid water
4. Temperature and Volume Dependence of the Viscosity of Water and Heavy Water at Low Temperatures
5. Nuclear Quantum Effects in Water and Aqueous Systems: Experiment, Theory, and Current Challenges
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