A computational study on ligand assisted vs. ligand participation mechanisms for CO2 hydrogenation: importance of bifunctional ligand based catalysts-Reference-Cited by-同舟云学术

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A computational study on ligand assisted vs. ligand participation mechanisms for CO2 hydrogenation: importance of bifunctional ligand based catalysts

Published:2019 Issue:7 Volume:21 Page:3932-3941
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Mandal Shyama Charan¹²³⁴⁵^ORCID,Rawat Kuber Singh¹²³⁴⁵^ORCID,Pathak Biswarup¹²³⁴⁵^ORCID

Affiliation:

1. Discipline of Chemistry

2. Indian Institute of Technology Indore

3. Simrol

4. Indore 453552

5. India

Abstract

Bifunctional aminomethyl based Mn(i) catalysts favour a revised Noyori type mechanism for the CO₂ hydrogenation reaction.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research

University Grants Commission

Ministry of Human Resource Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06714G

Reference80 articles.

1. Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons

2. Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities

3. Synthesis of formates from alcohols, carbon dioxide, and hydrogen catalysed by a combination of group VIII transition-metal complexes and tertiary amines

4. CATALYTIC FIXATION OF CARBON DIOXIDE TO FORMIC ACID BY TRANSITION-METAL COMPLEXES UNDER MILD CONDITIONS

5. Direct formation of formic acid from carbon dioxide and dihydrogen using the [{Rh(cod)Cl}2]–Ph2P(CH2)4PPh2catalyst system

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