Multiple activations of CH bonds in arenes and heteroarenes
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of South Carolina
3. Columbia
4. USA
Abstract
Re2(CO)8(μ-C6H5)(μ-H) reacts with anthracene four times to yield the quadruply CH activated complex [Re2(CO)8(μ-H)]4(μ-η2-1,2-μ-η2-3,4-μ-η2-5,6-μ-η2-7,8-C14H6).
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01584A
Reference62 articles.
1. C–H activation
2. Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution
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4. Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect
5. The molecular and electronic structure of carbon–hydrogen bond activation and transition metal assisted hydrogen transfer
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