An intramolecular Heck reaction of enol ethers involving β-alkoxyl elimination followed by the β-hydride elimination process: access to (Z)-ortho-formyl/keto-cinnamates-Reference-Cited by-同舟云学术

An intramolecular Heck reaction of enol ethers involving β-alkoxyl elimination followed by the β-hydride elimination process: access to (Z)-ortho-formyl/keto-cinnamates

Published:2019 Issue:96 Volume:55 Page:14422-14425
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sun Manman¹²³⁴,Wu Haibo⁵⁶⁷⁸⁴,Wu Haijian¹²³⁴,Wang Zhiming¹²³⁴^ORCID

Affiliation:

1. Advanced Research Institute and Department of Chemistry

2. Taizhou University

3. Taizhou 318000

4. P. R. China

5. The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education)

6. Department of Chemistry

7. Tsinghua University

8. Beijing 100084

Abstract

A highly regio- and stereoselective intramolecular Heck reaction of enol ethers involving β-alkoxyl elimination followed by the β-hydride elimination process has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC08133J

Reference41 articles.

1. Nonenzymatic Dynamic Kinetic Resolution of in situ Generated Hemithioacetals: Access to 1,3-Disubstituted Phthalans

2. Catalytic 1,2-dihydronaphthalene and E-aryl-diene synthesis via CoIII–Carbene radical and o-quinodimethane intermediates

3. CoIII–Carbene Radical Approach to Substituted 1H-Indenes

4. FeCl3 mediated synthesis of substituted indenones by a formal [2+2] cycloaddition/ring opening cascade of o-keto-cinnamates

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Novel oxoisochromene synthesisviachemoselective O–H insertion of 1,3-dicarbonyl compounds and subsequent Pd-catalyzed intramolecular arylation reaction;New Journal of Chemistry;2023

2. Synthesis, bio-physical and anti-leishmanial studies of some novel indolo[3,2-a]phenanthridine derivatives;Bioorganic Chemistry;2022-06

3. Vinylogous Elimination/C–H Functionalization/Allylation Cascade Reaction of Allenoate Adducts: Synthesis of Ring-Fused Dihydropyridinones;Organic Letters;2020-10-12