Stable and twisted 5,6:12,13-dinaphthozethrene from angular π-extension-Reference-Cited by-同舟云学术

Stable and twisted 5,6:12,13-dinaphthozethrene from angular π-extension

Published:2021 Issue:76 Volume:57 Page:9712-9715
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hu Jinlian¹,Xiang Qin¹,Xu Jun²,Xu Zhanqiang¹,Chen Guang³^ORCID,Sun Zhe¹^ORCID

Affiliation:

1. Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin university, 92 Weijin Road, Tianjin 300072, China

2. Health Science Platform, Tianjin University, 92 Weijin Road, Tianjin 300072, China

3. Shaanxi Key Laboratory of Chemical Additives for Industry, Key Laboratory of Chemical Additives for China National Light Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xian 710021, China

Abstract

Herein, we describe a concise and efficient synthesis of an angularly extended stable zethrene derivative 1, designed to have more benzenoid rings in the closed-shell resonance form.

Funder

Natural Science Foundation of Tianjin City

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04113D

Reference26 articles.

1. Aromatische Kohlenwasserstoffe, LXX. Mitteil. 1) : Zethren (1.12; 6.7‐Dibenztetracen)

2. Zethrenes, Extended p-Quinodimethanes, and Periacenes with a Singlet Biradical Ground State

3. Highly Twisted 1,2:8,9-Dibenzozethrenes: Synthesis, Ground State, and Physical Properties

4. Kinetically Blocked Stable 5,6:12,13-Dibenzozethrene: A Laterally π-Extended Zethrene with Enhanced Diradical Character

5. Dibenzoheptazethrene Isomers with Different Biradical Characters: An Exercise of Clar’s Aromatic Sextet Rule in Singlet Biradicaloids

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