Affiliation:
1. School of Chemistry, Chemical Engineering and Biotechnology, 21 Nanyang Link, 637371 Singapore
Abstract
ACu(OTf)2/Fe(OTf)3-promoted facile and stereoselective synthesis of 2,3-unsaturated glycosides through Ferrier rearrangement of rationally designed glycals with C3-CCBz. The dual roles of the metal catalysts in the reaction are explored with DFT.
Funder
Nanyang Technological University
Ministry of Education - Singapore
National Research Foundation Singapore
Publisher
Royal Society of Chemistry (RSC)