Light-active azaphenalene alkoxyamines: fast and efficient mediators of a photo-induced persistent radical effect-Reference-Cited by-同舟云学术

Light-active azaphenalene alkoxyamines: fast and efficient mediators of a photo-induced persistent radical effect

Published:2016 Issue:83 Volume:6 Page:80328-80333
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bottle Steven E.¹²³⁴⁵,Clement Jean-Louis⁶⁷⁸⁹¹⁰,Fleige Mirco¹²³⁴⁵,Simpson Emily M.¹²³⁴⁵,Guillaneuf Yohann⁶⁷⁸⁹¹⁰,Fairfull-Smith Kathryn E.¹²³⁴⁵,Gigmes Didier⁶⁷⁸⁹¹⁰,Blinco James P.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry

2. Physics and Mechanical Engineering

3. Science and Engineering Faculty

4. Queensland University of Technology

5. Brisbane

6. Aix Marseille Univ

7. CNRS

8. ICR UMR 7273

9. 13397 Marseille

10. France

Abstract

Reported is the first example of an alkoxyamine that quantitatively yields a nitroxide upon light exposure. The alkoxyamine is used to generate a light driven persistent radical effect and applied to radical insertion, exchange and polymerization reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA18500B

Reference40 articles.

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3. Tin-Free Radical Cyclization Reactions Using the Persistent Radical Effect

4. SG1 based alkoxyamines as radical initiators for the synthesis of lactones and lactames

5. Nitroxyl Radical Reactions with 4-Pentenyl- and Cyclopropylketenes: New Routes to 5-Hexenyl- and Cyclopropylmethyl Radicals

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