The Jahn–Teller effect in the presence of partial isotopic substitution: the B̃1E′′ state of NH2D and NHD2
Author:
Affiliation:
1. Department of Molecular and Laser Physics
2. Radboud University Nijmegen
3. IMM-FNWI
4. Nijmegen
5. The Netherlands
6. School of Chemistry
7. University of Bristol
8. Bristol
9. UK BS8 1TS
Abstract
A simple linear and quadratic force field model for the lifting of the degeneracy on asymmetric isotopic substitution in degenerate electronic states subject to a weak Jahn–Teller effect.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01299F
Reference22 articles.
1. Quantitative insights about molecules exhibiting Jahn-Teller and related effects
2. State-to-state resolved differential cross sections for rotationally inelastic scattering of ND3with He
3. Production of cold beams of ND3 with variable rotational state distributions by electrostatic extraction of He and Ne buffer-gas-cooled beams
4. The1E″ state of NH3: the Jahn-Teller effect revealed by infrared-optical double resonance
5. The B̃ 1E‘ state of ammonia: Sub‐Doppler spectroscopy at vacuum ultraviolet energies
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