An expanded halogen bonding scale using astatine-Reference-Cited by-同舟云学术

An expanded halogen bonding scale using astatine

Published:2021 Issue:32 Volume:12 Page:10855-10861
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Lu¹,Rahali Seyfeddine²³,Maurice Rémi¹^ORCID,Gomez Pech Cecilia¹²^ORCID,Montavon Gilles¹,Le Questel Jean-Yves²,Graton Jérôme²^ORCID,Champion Julie¹,Galland Nicolas²^ORCID

Affiliation:

1. SUBATECH UMR 6457, CNRS, IMT Atlantique, Université de Nantes, 4 Rue Alfred Kastler, 44307 Nantes, France

2. Université de Nantes, CNRS, CEISAM UMR 6230, 44000 Nantes, France

3. Department of Chemistry, College of Science and Arts, Qassim University, Ar Rass, Saudi Arabia

Abstract

Based on the halogen bonding between astatine monoiodide (AtI) and 16 Lewis bases, the newly established pKBAtI scale indicates that the halogen bond basicity of AtI follows the order C ≤ O ≤ S ≈ Se for the acceptor atomic site.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02133H

Reference43 articles.

1. Definition of the halogen bond (IUPAC Recommendations 2013)

2. The Halogen Bond

3. Molecular Recognition in Chemical and Biological Systems