Structural evolution from exohedral to endohedral geometries, dynamical fluxionality, and structural forms of medium-sized anionic and neutral Au2Sin (n = 8

Structural evolution from exohedral to endohedral geometries, dynamical fluxionality, and structural forms of medium-sized anionic and neutral Au2Sin (n = 8–20) clusters

Published:2020 Issue:44 Volume:22 Page:25606-25617
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lu Sheng-Jie¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering

2. Heze University

3. Heze

4. China

5. Beijing National Laboratory for Molecular Sciences

Abstract

Au₂Si₈⁻, Au₂Si₉⁻, Au₂Si₁₃⁻, Au₂Si₁₅⁻, _Au2Si₁₇⁻ anions and Au₂Si₁₃, Au₂Si_{14, Au2}Si₁₇ neutrals show dynamical fluxionality. In addition, the odd-even alternations of chemical stabilities are observed in the anionic and neutral Au₂Si_n clusters.

Funder

Natural Science Foundation of Shandong Province

Heze University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03825C

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