Greener photocatalytic route to the hetero-selective Glaser coupling reaction: role of hole/oxygen in air

Author:

Bag Subhendu Sekhar12ORCID,Sinha Sayantan2,Singh Siddharth1,Golder Animes K.23

Affiliation:

1. Chemical Biology/Genomics Laboratory, Department of Chemistry, IIT Guwahati, India

2. Center for the Environment, IIT Guwahati, India

3. Department of Chemical Engineering, IIT Guwahati, India

Abstract

Designed nano-photocatalyst [CuII@TiO2] is efficient for heteroselective Glaser coupling in green solvent with excellent turn-over-number. Light and hole/O2 in air maintain the catalytic cycle achieving spatial/temporal control of the reaction.

Funder

Department of Biotechnology , Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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