Fine-regulation of gradient gate-opening in nanoporous crystals for sieving separation of ternary C3 hydrocarbons

Author:

Liu Shuang1,Huang Yuhang2,Wan Jingmeng2,Zheng Jia-Jia3,Krishna Rajamani4ORCID,Li Yi2,Ge Kai2,Tang Jie2,Duan Jingui2ORCID

Affiliation:

1. Henan Engineering Research Center for Green Synthesis of Pharmaceuticals, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, China

2. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

3. Laboratory of Theoretical and Computational Nanoscience, National Center for Nanoscience and Technology, Chinese Academy of Sciences, Beijing 100190, China

4. Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

Abstract

We present a fine regulation of the gradient gate-opening in a series of soft nanoporous crystals, of which NTU-65-CoTi demonstrates an unprecedented breakthrough of ternary C3H4/C3H6/C3H8 mixture sieving separation in one-step.

Funder

Education Department of Henan Province

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

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