EDA mediated S–N bond coupling of nitroarenes and sodium sulfinate salts

Author:

Lasso Juan D.1ORCID,Castillo-Pazos Durbis J.1ORCID,Sim Malcolm1,Barroso-Flores Joaquín2ORCID,Li Chao-Jun1ORCID

Affiliation:

1. Department of Chemistry, FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. W., Montreal, Quebec H3A 0B8, Canada

2. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM, Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano, Toluca, Estado de México C. P. 50200, México

Abstract

We report the design and application of a sulfinate–nitroarene electron donor–acceptor (EDA) complex and its subsequent use in the first visible light-mediated and catalyst-free synthesis of N-hydroxy-sulfonamides.

Funder

Natural Sciences and Engineering Research Council of Canada

Consejo Nacional de Ciencia y Tecnología

Fonds de recherche du Québec – Nature et technologies

Canada Research Chairs

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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