External control over tautomeric distribution and inter-conversion: new insights into the realm of catalyzed tautomerization
Author:
Affiliation:
1. Department of Basic Science & Humanities
2. Institute of Engineering and Management
3. Kolkata 700091
4. India
5. Department of Chemistry
6. Scottish Church College
7. Kolkata-700006
Abstract
Relative stabilities of tautomers and tautomeric barriers are extensively modulated by use of carboxylic acids and amine bases.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA03233D
Reference22 articles.
1. Tautomerism: Methods and Theories, ed. L. Antonov, Wiley-VCH, Weinheim, 1st edn, 2013 and references therein
2. Nucleic Acid Bases in the Gas Phase
3. Carboxylic Acid Catalyzed Keto-Enol Tautomerizations in the Gas Phase
4. Barrierless tautomerization of Criegee intermediates via acid catalysis
5. Hydrolysis of Ketene Catalyzed by Formic Acid: Modification of Reaction Mechanism, Energetics, and Kinetics with Organic Acid Catalysis
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