Shining light on tryptamine-derived isocyanides: access to constrained spirocylic scaffolds-Reference-Cited by-同舟云学术

Shining light on tryptamine-derived isocyanides: access to constrained spirocylic scaffolds

Published:2024 Issue:18 Volume:15 Page:6867-6873
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Minghui¹^ORCID,Saya Jordy M.¹^ORCID,Han Peiliang²,Walia Rajat³^ORCID,Pradhan Bapi⁴^ORCID,Honing Maarten²,Ranjan Prabhat¹^ORCID,Orru Romano V. A.¹^ORCID

Affiliation:

1. Aachen Maastricht Institute for Biobased Materials (AMIBM), Maastricht University, Urmonderbaan 22, 6167 RD Geleen, The Netherlands

2. Maastricht MultiModal Molecular Imaging Institute (M4i), Division of Imaging Mass Spectrometry, Maastricht University, Universiteitssingel 50, 6229 ER Maastricht, The Netherlands

3. Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR

4. Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, 3001 Leuven, Belgium

Abstract

Tryptamine-derived isocyanides form aggregates at higher concentration that can form a charge transfer complex under visible light irradiation thus enabling a crucial single electron transfer step to generate carbon-based-radical intermediates.

Funder

HORIZON EUROPE Marie Sklodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06304F

Reference40 articles.

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3. Photocatalytical and Photochemical Generation of Imidoyl Radicals: Synthetic Applications

4. Isocyanide‐Based Multicomponent Reactions Promoted by Visible Light Photoredox Catalysis

5. Photo-Driven Synthesis of C6-Polyfunctionalized Phenanthridines from Three-Component Reactions of Isocyanides, Alkynes, and Sulfinic Acids by Electron Donor–Acceptor Complex