In situ X-ray absorption fine structure study on the polymerization of isoprene assisted by Nd-based ternary catalysts-Reference-Cited by-同舟云学术

In situ X-ray absorption fine structure study on the polymerization of isoprene assisted by Nd-based ternary catalysts

Published:2017 Issue:24 Volume:7 Page:14413-14421
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Guo H. L.¹²³⁴⁵,Bi J. F.⁶⁷⁸⁹⁴,Wu Q. Y.⁵⁸¹⁰¹¹⁴,Wang J. Y.⁵⁸¹⁰¹¹⁴,Shi W. Q.⁵⁸¹⁰¹¹⁴,Zhang X. Q.⁶⁷⁸⁹⁴,Jiang S. C.¹²³⁴,Wu Z. H.⁵⁸¹⁰¹¹⁴^ORCID

Affiliation:

1. School of Materials Science and Engineering

2. Tianjin University

3. Tianjin 300072

4. China

5. Institute of High Energy Physics

6. Research Center of High Performance Synthetic Rubber

7. Changchun Institute of Applied Chemistry

8. Chinese Academy of Sciences

9. Changchun 130022

10. Graduate University of Chinese Academy of Sciences

11. Beijing 100049

Abstract

Polymerization processes of isoprene catalyzed by four catalysts with different alkylaluminums were detected by in situ XAFS technique. The catalytic mechanism of the neodymium-based ternary catalyst was discussed based on the structure information.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA01249G

Reference50 articles.

1. Quasi-Living trans-1,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Bearing a Chiral (S,S)-Bis(oxazolinylphenyl)amido Ligand

2. Discrete Lanthanide Aryl(alk)oxide Trimethylaluminum Adducts as Isoprene Polymerization Catalysts

3. Lanthanide Triflates-Mediated Emulsion Cationic Polymerization of p-Alkoxystyrenes in Aqueous Media

4. Controlled Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Rare-Earth Perfluoroalkanesulfonates and Perfluoroalkanesulfonimides

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