Anomalous π-backbonding in complexes between B(SiR3)3 and N2: catalytic activation and breaking of scaling relations-Reference-Cited by-同舟云学术

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Anomalous π-backbonding in complexes between B(SiR₃)₃ and N₂: catalytic activation and breaking of scaling relations

Published:2023 Issue:31 Volume:25 Page:21006-21019
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Brinck Tore¹^ORCID,Sahoo Suman Kalyan¹

Affiliation:

1. Department of Chemistry, CBH, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden

Abstract

Lewis acids of the types B(SiR3)3 and B(GeR3)3 bind N2 and CO with anomalously short and strong B–N or B–C bonds.

Funder

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00248A

Reference56 articles.

1. Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

2. A bound reaction intermediate sheds light on the mechanism of nitrogenase

3. Electrochemical Ammonia Synthesis—The Selectivity Challenge

4. Dinitrogen Coordination Chemistry: On the Biomimetic Borderlands

5. A theoretical evaluation of possible transition metal electro-catalysts for N2reduction

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1. p-block doped semi-metallic xenes as highly selective and efficient transition-metal free single atom catalysts for electrochemical CO reduction;Journal of Materials Chemistry A;2024

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