Unveiling the high reactivity of experimental pseudodiradical azomethine ylides within molecular electron density theory

Author:

Ríos-Gutiérrez Mar1ORCID,Domingo Luis R.1ORCID,Jasiński Radomir2ORCID

Affiliation:

1. Department of Organic Chemistry, University of Valencia, Dr Moliner 50, Burjassot, 46100 Valencia, Spain

2. Faculty of Chemical Engineering and Technology, Department of Organic Chemistry and Technology, Cracow University of Technology, Warszawska 24, 31-155 Cracow, Poland

Abstract

The variable reactivity of the first known experimental pseudodiradical azomethine ylide is characterized within the molecular electron density theory.

Funder

Ministerio de Ciencia e Innovación

Universitat de València

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference61 articles.

1. W.Carruthers , Some Modern Methods of Organic Synthesis , Cambridge University Press , Cambridge, UK , 2nd edn, 1978

2. A.Padwa , 1,3-Dipolar Cycloaddition Chemistry , Wiley-Interscience , New York, NY, USA , 1984 , vol. 1 and 2

3. W.Carruthers , Cycloaddition Reactions in Organic Synthesis , Pergamon , Oxford, UK , 1990

4. A.Padwa and W. H.Pearson , Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products , John Wiley & Sons, Inc ., New York, NY, USA , 2002 , vol. 59

5. Molecular Electron Density Theory: A Modern View of Reactivity in Organic Chemistry

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