Half-sandwich type rhodium(iii)–aminohydroxamate complexes: the role of the position of the amino group in metal ion binding

Author:

Parajdi-Losonczi Péter László1234ORCID,Buglyó Péter1234ORCID,Skakalova Hana56789ORCID,Kasparkova Jana56789ORCID,Lihi Norbert10234ORCID,Farkas Etelka1234ORCID

Affiliation:

1. Department of Inorganic and Analytical Chemistry

2. University of Debrecen

3. H-4032 Debrecen

4. Hungary

5. Department of Biophysics

6. Faculty of Science

7. Palacky University

8. 77146 Olomouc

9. Czech Republic

10. MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group

Abstract

Relative order of the pH-dependent conditional stability of the hydroxamate type (O,O) and (Namino,Nhydroxamato) chelates determines the coordination modes in the various mono- and dinuclear complexes of [(η5-Cp*)RhIII(H2O)3]2+ with α-, β- and γ-aminohydroxamic acids.

Funder

European Regional Development Fund

Országos Tudományos Kutatási Alapprogramok

Emberi Eroforrások Minisztériuma

Univerzita Palackého v Olomouci

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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