Silicon as a powerful control element in HDDA chemistry: redirection of innate cyclization preferences, functionalizable tethers, and formal bimolecular HDDA reactions-Reference-Cited by-同舟云学术

Silicon as a powerful control element in HDDA chemistry: redirection of innate cyclization preferences, functionalizable tethers, and formal bimolecular HDDA reactions

Published:2021 Issue:41 Volume:12 Page:13902-13908
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lynn Mandy¹,Pierson Smela Merrick¹^ORCID,Hoye Thomas R.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN 55455, USA

Abstract

A designer silicon-containing linker enables HDDA chemistry that complements known modes of reactivity. Subsequent removal of the Si liberates a benzenoid product that is formally the result of an intermolecular HDDA reaction.

Funder

National Institute of General Medical Sciences

Masonic Cancer Center, University of Minnesota

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04082K

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