2.2.2-Cryptand complexes of neptunium(iii) and plutonium(iii)-Reference-Cited by-同舟云学术

2.2.2-Cryptand complexes of neptunium(iii) and plutonium(iii)

Published:2022 Issue:7 Volume:58 Page:997-1000
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Goodwin Conrad A. P.¹^ORCID,Ciccone Sierra R.²^ORCID,Bekoe Samuel²^ORCID,Majumdar Sourav²^ORCID,Scott Brian L.³^ORCID,Ziller Joseph W.²^ORCID,Gaunt Andrew J.¹^ORCID,Furche Filipp²^ORCID,Evans William J.²^ORCID

Affiliation:

1. Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA

2. Department of Chemistry, University of California Irvine, Irvine, CA 92697-2025, USA

3. Materials Physics & Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA

Abstract

The THF-soluble [An(crypt)(OTf)2][OTf] complexes for An = Np and Pu were synthesized from AnI3(THF)4 starting materials based on pilot studies of the An = U system. 5f3 U(iii), 5f4 Np(iii), and 5f5 Pu(iii) electron configurations are indicated by DFT analysis of their UV-visible-NIR spectra.

Funder

Basic Energy Sciences

Laboratory Directed Research and Development

Office of Advanced Cyberinfrastructure

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05904A

Reference48 articles.

1. F. D.White and M. L.Marsh , Handbook on the Physics and Chemistry of Rare Earths , 2019 , ch. Including Actinides, vol. 55, pp. 123–158

2. Organometallic Neptunium Chemistry

3. Transuranic Computational Chemistry

4. Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

5. Evaluating f-Element Bonding from Structure and Thermodynamics

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