Theoretical study of the BINOL–zinc complex-catalyzed asymmetric inverse-electron-demand imino Diels–Alder reaction: mechanism and stereochemistry-Reference-Cited by-同舟云学术

Theoretical study of the BINOL–zinc complex-catalyzed asymmetric inverse-electron-demand imino Diels–Alder reaction: mechanism and stereochemistry

Published:2015 Issue:113 Volume:5 Page:93318-93330
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Li Weiyi¹²³⁴,Yang Na⁵⁶⁷⁴,Lv Yajing¹²³⁴

Affiliation:

1. School of Science

2. Xihua University

3. Chengdu

4. P. R. China

5. Institute of Nuclear Physics and Chemistry

6. China Academy of Engineering Physics

7. Mianyang

Abstract

The enantioselectivity originates from the hindrance of a BINOL ligand, and the exo-selectivity is achieved by the favored electrophilic/nucleophilic interaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17981E

Reference101 articles.

1. Asymmetric Hetero Diels-Alder Reactions

2. Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles

3. Recent synthetic developments in a powerful imino Diels–Alder reaction (Povarov reaction): application to the synthesis of N-polyheterocycles and related alkaloids

4. Stereoselective Aza-Diels-Alder Reactions

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