Synthesis and characterization of NiAl-hydride heterometallics: perturbing electron density within Al–H

Synthesis and characterization of NiAl-hydride heterometallics: perturbing electron density within Al–H–Ni subunits

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gonzalez Aleida G.¹,Gonzalez Fernando¹,De Leon Edgardo¹,Birkhoff Kaitlyn M.²^ORCID,Yruegas Sam²^ORCID,Chen Haoyuan³⁴,Shoshani Manar M.¹⁵^ORCID

Affiliation:

1. School of Integrated Biological and Chemical Sciences, University of Texas Rio Grande Valley, Brownsville, Texas, 78520, USA

2. Department of Chemistry, Rice University, Houston, Texas, 77005, USA

3. Department of Physics and Astronomy, University of Texas Rio Grande Valley, Edinburg, Texas, 78539, USA

4. Department of Chemistry, Southern Methodist University, Dallas, Texas, 75275, USA

5. Department of Chemistry, University of Kansas, Lawrence, Kansas, 66045, USA

Abstract

Heterobimetallic NiAl-hydride complexes with varying electronic profiles and charge are synthesized and interrogated in their degree of Ni–H character.

Funder

National Science Foundation

Cancer Prevention and Research Institute of Texas

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01786B

Reference90 articles.

1. Tuning metal–metal interactions for cooperative small molecule activation

2. Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

3. Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

4. Exterior decorating: Lewis acid secondary coordination spheres for cooperative reactivity

5. Cooperative heterometallic platforms enabling selective C–H bond activation and functionalization of pyridines