Palladium-catalyzed double coupling reaction of terminal alkynes with isocyanides: a direct approach to symmetrical N-aryl dialkynylimines-Reference-Cited by-同舟云学术

Palladium-catalyzed double coupling reaction of terminal alkynes with isocyanides: a direct approach to symmetrical N-aryl dialkynylimines

Published:2020 Issue:40 Volume:18 Page:8089-8093
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Xi Zhi-Wei¹²³⁴⁵,He Yan⁶⁷⁸⁹¹⁰,Liu Li-Qiu¹²³⁴⁵,Wang Ying-Chun¹²³⁴⁵^ORCID

Affiliation:

1. National Demonstration Center for Experimental Chemistry Education

2. Hunan Engineering Laboratory for Analyse and Drugs Development of Ethnomedicine in Wuling Mountains

3. Jishou University

4. Jishou 416000

5. P. R. China

6. Shanghai Key Laboratory of Functional Materials Chemistry

7. Key Laboratory for Advanced Materials

8. State Key Laboratory of Chemical Engineering and School of Chemistry & Molecular Engineering

9. East China University of Science and Technology

10. Shanghai

Abstract

We have synthesized symmetrical N-aryl dialkynylimines via the palladium-catalyzed double coupling reaction of terminal alkynes with isonitriles, and the obtained dialkynylimines could be readily converted into 2-iodobenzo[f]quinoline derivatives.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01604G

Reference39 articles.

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4. 3,4,5,6-Tetrasubstituted 2-Pyridone Synthesis via Nucleophilic Addition of Active Methine Compounds to Dialkynyl Imines Directed to the Synthesis of (-)-A58365A

5. Synthesis of Multi-Substituted 2-Iminopyridine by Conjugate Addition of Ethyl Cyanoacetate Derivatives to Alkynyl Imines

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