A series of pentanary inorganic supramolecular sulfides (A3X)[MB12(MS4)3] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B12S12 clusters
Author:
Affiliation:
1. School of Chemistry & Chemical Engineering
2. Yangzhou University
3. Yangzhou
4. P. R. China
Abstract
A series of multinary thiogallate- or thioindate-closo-dodecaborates synthesized by solid state reactions demonstrate second-harmonic generation behaviors.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QI/C7QI00396J
Reference38 articles.
1. Recent achievements on middle and far-infrared second-order nonlinear optical materials
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3. Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures
4. [A3X][Ga3PS8] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds
5. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds
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