Construction of lanthanide single-molecule magnets with the “magnetic motif” [Dy(MQ)4]−-Reference-Cited by-同舟云学术

Construction of lanthanide single-molecule magnets with the “magnetic motif” [Dy(MQ)4]−

Published:2017 Issue:11 Volume:4 Page:1776-1782
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Lyu Deng-Ping¹²³⁴⁵,Zheng Jie-Yu¹²³⁴⁵,Li Quan-Wen¹²³⁴⁵,Liu Jun-Liang¹²³⁴⁵^ORCID,Chen Yan-Cong¹²³⁴⁵^ORCID,Jia Jian-Hua¹²³⁴⁵^ORCID,Tong Ming-Liang¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of Chemistry

3. Sun Yat-Sen University

4. 510275 Guangzhou

5. P. R. China

Abstract

[Dy₂(MQ)₄(NO₃)₃]⁺ is SMM-silent (SMM = single-molecule magnet) owing to the unfavourable magnetic interactions. Introducing an additional “magnetic motif” [Dy(MQ)₄]⁻ to diminish such interactions gave a trinuclear [Dy₃(MQ)₈(NO₃)], which behaves as an SMM.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QI/C7QI00393E

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