Influence of interstitial UO22+ doping on the valence control of Eu and energy transfer to substitutional Eu3+ and Sm3+ in SrBPO5-Reference-Cited by-同舟云学术

Influence of interstitial UO22+ doping on the valence control of Eu and energy transfer to substitutional Eu3+ and Sm3+ in SrBPO5

Published:2021 Issue:42 Volume:50 Page:15071-15083
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vinodkumar P.¹²^ORCID,Padhi R. K.³^ORCID,Panda Sitakanta¹²,Ramakrishna P.¹⁴,Panigrahi B. S.¹²

Affiliation:

1. Homi Bhabha National Institute, Kalpakkam 603102, Tamil Nadu, India

2. Safety, Quality and Resource Management Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu, India

3. Material Chemistry and Metal Fuel Cycle Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu, India

4. Safety Research Institute, AERB, Kalpakkam 603102, Tamil Nadu, India

Abstract

Europium got stabilized as Eu2+ and Eu3+ and Samarium got stabilized as Sm3+ in stillwellite SrBPO5. The interstitial uranium co-doping caused energy transfer to Eu3+ and Sm3+ and influenced the ratio of the Eu3+ and Eu2+ ions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02657G

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