Ratiometric mixed Eu–Tb metal–organic framework as a new cryogenic luminescent thermometer

Author:

N’Dala-Louika Isis12345,Ananias Duarte678910ORCID,Latouche Camille12345ORCID,Dessapt Rémi12345,Carlos Luís D.678910ORCID,Serier-Brault Hélène12345ORCID

Affiliation:

1. Institut des Matériaux Jean Rouxel

2. Université de Nantes

3. CNRS

4. 44322 Nantes cedex 3

5. France

6. Department of Chemistry and Physics

7. CICECO

8. Aveiro Institute of Materials

9. University of Aveiro

10. Aveiro

Abstract

The first example of a dual-emitting luminescent thermometer based on lanthanide isophthalate exhibiting a maximum relative sensitivity of 3.26% K−1, a temperature uncertainty of 0.07 K at 35.5 K, and a repeatability >99.9% between 12 and 230 K.

Funder

Fundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference30 articles.

1. Mixed-Lanthanoid Metal–Organic Framework for Ratiometric Cryogenic Temperature Sensing

2. C. D. S. Brites , A.Millán and L. D.Carlos, in Handbook on the Physics and Chemistry of Rare Earths, ed. J.-C. Bünzli and V. K. Pecharsky, Elsevier, Amsterdam, Science B.V., 2016, 49, 339

3. Lanthanide Organic Framework Luminescent Thermometers

4. Lanthanide-Organic Framework Nanothermometers Prepared by Spray-Drying

5. A cryogenic luminescent ratiometric thermometer based on a lanthanide phosphonate dimer

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