Regulating intermediate adsorption and H<sub>2</sub>O dissociation on a diatomic catalyst to promote electrocatalytic nitrate reduction to ammonia-Reference-Cited by-同舟云学术

Regulating intermediate adsorption and H₂O dissociation on a diatomic catalyst to promote electrocatalytic nitrate reduction to ammonia

Published:2024 Issue: Volume: Page:
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Zhang Xiaoxue¹²,Liu Xiaokang¹²,Huang Zhen-Feng¹²³^ORCID,Gan Li¹²,Zhang Shishi¹²,Jia Ru¹²,Ajmal Muhammad¹²,Pan Lun¹²³^ORCID,Shi Chengxiang¹²³^ORCID,Zhang Xiangwen¹²³,Yang Guidong⁴,Zou Ji-Jun¹²³^ORCID

Affiliation:

1. Key Laboratory for Green Chemical Technology of the Ministry of Education, Institution School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

2. Collaborative Innovative Centre of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

3. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

4. XJTU-Oxford International Joint Laboratory for Catalysis, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China

Abstract

Cu–Fe–N–C demonstrates excellent electrocatalytic activity for nitrate reduction by optimizing intermediate adsorption and generating a substantial supply of H* for the thorough hydrogenation of the N-containing intermediates.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/EE/D4EE02747G

Reference43 articles.

1. Current and future role of Haber–Bosch ammonia in a carbon-free energy landscape

2. Modulating Metal‐Nitrogen Coupling in Anti‐Perovskite Nitride via Cation Doping for Efficient Reduction of Nitrate to Ammonia

3. Potassium hydride-intercalated graphite as an efficient heterogeneous catalyst for ammonia synthesis

4. A Zn–nitrite battery as an energy-output electrocatalytic system for high-efficiency ammonia synthesis using carbon-doped cobalt oxide nanotubes