Alkene insertion reactivity of a <i>o</i>-carboranyl-substituted 9-borafluorene-Reference-Cited by-同舟云学术

Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene

Published:2022 Issue:25 Volume:13 Page:7492-7497
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bischof Tobias¹²,Guo Xueying³^ORCID,Krummenacher Ivo¹²,Beßler Lukas¹²,Lin Zhenyang³^ORCID,Finze Maik¹²^ORCID,Braunschweig Holger¹²^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

3. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, P. R. China

Abstract

A 9-carboranyl-substituted 9-borafluorene is reported, which is capable of undergoing efficient ring expansion to 6,7-dihydroborepins by a previously unknown alkene insertion.

Funder

Julius-Maximilians-Universität Würzburg

Hong Kong University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02750J

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