O–H bond oxidation by a monomeric MnIII–OMe complex-Reference-Cited by-同舟云学术

O–H bond oxidation by a monomeric MnIII–OMe complex

Published:2015 Issue:7 Volume:44 Page:3295-3306
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wijeratne Gayan B.¹²³⁴,Day Victor W.¹²³⁴,Jackson Timothy A.¹²³⁴

Affiliation:

1. Department of Chemistry and Center for Environmentally Beneficial Catalysis

2. University of Kansas

3. KS 66045

4. USA

Abstract

The structurally characterized [Mn^III(OMe)(dpaq)]⁺ complex is the first example of a stable Mn^III–OMe complex that can activate substrate O–H bonds with bond dissociation free energies up to 78.5 kcal mol⁻¹ in acetonitrile.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03546A

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