Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex-Reference-Cited by-同舟云学术

Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex

Published:2015 Issue:3 Volume:6 Page:2060-2067
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Polukeev Alexey V.¹²³⁴⁵,Marcos Rocío⁶⁷⁸⁹⁵,Ahlquist Mårten S. G.⁶⁷⁸⁹⁵,Wendt Ola F.¹²³⁴⁵

Affiliation:

1. Centre for Analysis and Synthesis

2. Department of Chemistry

3. Lund University

4. 22100 Lund

5. Sweden

6. Division of Theoretical Chemistry & Biology

7. School of Biotechnology

8. KTH Royal Institute of Technology

9. SE-106 91 Stockholm

Abstract

Iridium can mediate a reversible intramolecular coupling reaction involving up to four unactivated C_sp3–H bonds, to give a carbon–carbon double bond.

Funder

Vetenskapsrådet

Knut och Alice Wallenbergs Stiftelse

Crafoordska Stiftelsen

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03839H

Reference54 articles.

1. Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

2. Activation of C−H Bonds by Metal Complexes

3. Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect

4. Understanding and exploiting C–H bond activation

5. C–H activation

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