From mixed group 13 cations [M(AlCp*)3]+ (M = Ga/In/Tl) to an Al4+ cluster-Reference-Cited by-同舟云学术

From mixed group 13 cations [M(AlCp*)₃]⁺ (M = Ga/In/Tl) to an Al₄⁺ cluster

Published:2022 Issue:41 Volume:13 Page:12078-12086
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dabringhaus Philipp^ORCID,Krossing Ingo¹^ORCID

Affiliation:

1. Albert-Ludwigs-Universität Freiburg, Institute for Inorganic and Analytical Chemistry, Freiburg Materials Research Center FMF, Albertstraße 21, 79104 Freiburg i. Br., Germany

Abstract

Mixed low-valent group 13 cations with formally reduced metal atoms have been prepared via addition of [(AlCp*)4] to the low-valent cation salts of Ga, In and Tl. Addition of an aza-crown ether resulted in isomerization to a novel Al4+ cluster.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04637G

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