Base induced rearrangement of an α-bromophosphonamidate: stereochemistry of ring opening of the azaphosphiridine oxide intermediate as revealed by X-ray crystallography
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1993/C3/C39930001826
Reference17 articles.
1. Reactions of N-phenyl α-halogenophosphonamidates with alkoxide: migration of the anilino group from phosphorus to the α carbon atom
2. Evidence for cyclic azaphosphiridine oxide intermediates in the methoxide-induced rearrangements of N-alkyl α-chlorophosphonamidates: formation of phosphoramidates as well as α-aminophosphonates
3. Phosphor in Dreiringen
4. Dreigliedrige Heterocyclen Phosphonsäureesterhydrazide durch Alkoholat-induzierte Umlagerung vonN-Chlorphosphonsäurediamiden
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1. Azaphosphiridines: challenges and perspectives;Dalton Transactions;2021
2. Analysis of P–O–C, P–S–C and P–O–P angles: a database survey completed with four new X-ray crystal structures;Structural Chemistry;2016-08-02
3. Properties and Reactions of Phosphonic and Phosphinic Acids and their Derivatives;PATAI'S Chemistry of Functional Groups;2009-12-15
4. The difference in reactivity of (−)-mono and dimenthyl vs. diethyl alkylphosphonates in the α-lithiation reaction: Carbanionic synthesis of unknown (−)-dimenthyl 1-iodoalkylphosphonates and their first use in the radical iodine atom transfer addition (I-ATRA) and cyclisation (I-ATRC) reactions;Journal of Organometallic Chemistry;2007-02
5. Stereochemistry of the methoxide induced rearrangement of an α-bromophosphonamidate: cleavage of the P–N and P–C bonds in the azaphosphiridine oxide intermediate 1;Journal of the Chemical Society, Perkin Transactions 1;1997
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